By Norman H. March

In this introductory chemical physics textbook, the authors speak about the interactions, bonding, electron density, and experimental thoughts of loose molecules, and practice spectroscopic the right way to confirm molecular parameters, dynamics, and chemical reactions.

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G. C. Pimentel and R. D. Spratley, Chemical Bonding Clarified Through Quantum Mechanics, HoldenDay, San Francisco (1969). 35 Chemical Concepts and Experimental Techniques 36 Chapter One N. C. Pyper and I. P. Grant, Proc. Roy. Soc. A359, 525 (1978). E. J. Rosenbaum, Physical Chemistry, Appleton-Century Crofts, New York (1970). R. T. Sanderson, Science 114, 670 (1951). R. T. Sanderson, Chemical Periodicity, Reinhold, New York (1960). R. T. Sanderson, Inorganic Chemistry, Reinhold, New York (1967).

B. Moore, J. Chem. Phys. 54, 4072 (1971). M. Day and J. L. Selbin, Theoretical Inorganic Chemistry, Reinhold, New York (1969). R. L. De Kock and H. G. Gray, Chemical Structure and Bonding, Benjamin/Cummings, Menlo Park, CA (1980). W. H. Flygare, Molecular Structure and Dynamics, Prentice-Hall, Englewood Cliffs, NJ (1978). J. M. Hollas, High Resolution Spectroscopy, Butterworth, London (1982). J. M. Hollas, Modern Spectroscopy, John Wiley and Sons, New York (1987). J. L. Hollenberg, J. Chem. Educ.

In spite of the early history of the photoelectric effect, the experimental difficulties proved to be substantial, and it was not until around 1960 that photoelectron studies became a major branch of spectroscopy. (b) Interpretation in Terms of Molecular Orbitals In Chapters 4 and 6, we shall see that the generation of molecular orbitals (MOs) V'i(r), belonging to the molecule as a whole, via a one-body potential energy V(r) , lies deep in the many-electron problem. 24) The essential point to be discussed fully in Chapters 4 and 6 is then the construction of VCr).

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